{"id":442,"date":"2021-06-18T17:38:24","date_gmt":"2021-06-18T09:38:24","guid":{"rendered":"https:\/\/kelly.anjun.com.tw\/?page_id=442"},"modified":"2021-11-01T14:26:47","modified_gmt":"2021-11-01T06:26:47","slug":"%e5%85%89%e8%ad%9c%e5%84%80","status":"publish","type":"page","link":"https:\/\/www.anjun.com.tw\/en\/%e9%9b%b7%e5%b0%84\/%e9%9b%b7%e5%b0%84%e9%80%b1%e9%82%8a%e8%a8%ad%e5%82%99%e9%8a%b7%e5%94%ae\/atseva%e9%9b%b7%e5%b0%84\/%e5%85%89%e8%ad%9c%e5%84%80\/","title":{"rendered":"\u5149\u8b5c\u5100"},"content":{"rendered":"<div data-elementor-type=\"wp-page\" data-elementor-id=\"442\" class=\"elementor elementor-442\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-ec14f24 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"ec14f24\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-7608129\" data-id=\"7608129\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-86b9123 elementor-widget elementor-widget-spacer\" data-id=\"86b9123\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"spacer.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<div class=\"elementor-spacer\">\n\t\t\t<div class=\"elementor-spacer-inner\"><\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-2ffe16e elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"2ffe16e\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-top-column elementor-element elementor-element-ee836f6\" data-id=\"ee836f6\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-df16661 elementor-widget elementor-widget-text-editor\" data-id=\"df16661\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p><span style=\"color: #000000;\">Astrolabe tabletop femtosecond SFG\/CARS spectrometer<\/span><\/p><ul><li><p><span style=\"color: #000000;\">Femtosecond broadband combination SFG\/CARS spectrometer<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Unique vibrational spectroscopy tool for monitoring surface layers in real time<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Modular quick-interchangeable sample holdes for flat samples, crystals, liquid and electrochemical cells<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Cost-efficient: combines two powerful nonlinear probes, specifically designed to be shared among several research groups<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Compact tabletop design<\/span><\/p><\/li><\/ul>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-50 elementor-top-column elementor-element elementor-element-3cf765f\" data-id=\"3cf765f\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-8b58ab8 elementor-widget elementor-widget-image\" data-id=\"8b58ab8\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<img decoding=\"async\" width=\"196\" height=\"170\" src=\"https:\/\/www.anjun.com.tw\/wp-content\/uploads\/2021\/06\/Astrolabe_cut1-1.png\" class=\"attachment-large size-large wp-image-446\" alt=\"\" \/>\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-bb9f976 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"bb9f976\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-abca018\" data-id=\"abca018\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-dc45eb9 elementor-widget elementor-widget-text-editor\" data-id=\"dc45eb9\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<div id=\"panel-1293-1-0-1\" class=\"so-panel widget widget_sow-editor\" data-index=\"3\"><div class=\"so-widget-sow-editor so-widget-sow-editor-base\"><div class=\"siteorigin-widget-tinymce textwidget\"><h3><span style=\"color: #000000;\">1. General<\/span><\/h3><p><span style=\"color: #000000;\">Astrolabe is table-top nonlinear spectroscopy setup designed to be installed on 4&#215;8&#8242; (1200x2400mm) standard optical table. It consists of CPA (chirped-pulse amplification) Ti:Sapphire femtosecond laser source, femtosecond Optical Parametric Amplifier (OPA) as a source of tunable radiation, Air-spaced Fabry-Perot etalon for shaping 800nm pulses, beam delivery and conditioning system with computer-controlled delay line, gas-purged beams and sample boxes, with appropriate filters, attenuators and polarization control elements, modular sample holder and detection system consisting of spectrograph with CCD detector.<\/span><\/p><h4><span style=\"color: #000000;\"><strong>SFG spectroscopy: strengths of the method:<\/strong><\/span><\/h4><ul><li><p><span style=\"color: #000000;\">Specificity: probes surface layers but not the bulk of the substrate.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Sensitivity: readily detects surface concentrations less than a monolayer.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Uniqueness: optical probe with unmatched sensitivity to the surface symmetry, molecular orientation and disorder \u2013 determine the tilt of surface molecules, detect isomerisation such as kinking of molecular chains, surface disorder under pressure or due to chemical reaction, 2D phase-transitions and the like.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Reach: get to interfaces buried under layers of only partially IR-transparent material, enclosed in vacuum and liquid cells, easily relay the coherent SFG signal away from hard to reach areas without compromising sensitivity.<\/span><\/p><\/li><\/ul><h4><span style=\"color: #000000;\"><strong>Where does our system stand out:<\/strong><\/span><\/h4><ul><li><p><span style=\"color: #000000;\">Measure FAST &#8211; acquire 1000 spectral points in the time you would otherwise measure just one point in &#8220;traditional&#8221; scanning SFG setup. This allows for real-time monitoring of surface concentrations with submonolayer sensitivity. Alternatively this provides enough time to register weak SFG signal even if the sample is short-lived.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Look WIDE: Simultaneously monitor multiple peaks and their evolution in real time over 200cm<sup>-1\u00a0<\/sup>frequency range; not just the amplitudes, but also bandwidths and peak shapes in general; record minutes of &#8220;vibrational spectral movie&#8221; of your process.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Time-tested tabletop Ti:Sapphire CPA system \u2013 spend time on your experiment, not on laser alignment.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Powerful IR beam capable of overcoming strong absorption and reaching interfaces covered with water, e.g. in electrochemical cell.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Powerful visible beam: split out portion of it and use it to provide a pump with SFG signal serving as a probe for pump-probe experiment with picosecond time resolution.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Unique sample positioning system with fixed base plane allowing for rapid changes of dissimilar samples and complete sample cells, all that without the need for major realignment of the optics \u2013 several research groups can share one installation reconfiguring it for new experiment in a matter of minutes.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Quickly change from vertical sample orientation (good for flat solid samples) to horizontal orientation (suitable for electrochemical cells).<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Choose between copropagating IR-Visible beam geometry and on-sample crossing geometry \u2013 the former allowing for simple optical alignment; suitable for less experienced researches; use the latter if stray nonlinear optical effects has to be completely eliminated.<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">With minor realignment switch the system to CARS spectrometer mode, taking advantage of the same versatile sample holders and detection system. CARS, while not surface-sensitive, can complement SFG in cases where sample composition results in complicated vibrational spectra.Please read more on SFG in PDF section.<\/span><\/p><\/li><\/ul><\/div><\/div><\/div><div id=\"panel-1293-1-0-2\" class=\"so-panel widget widget_sow-editor\" data-index=\"4\"><div class=\"so-widget-sow-editor so-widget-sow-editor-base\"><div class=\"siteorigin-widget-tinymce textwidget\"><h3><span style=\"color: #000000;\">2. Specifications<\/span><\/h3><p><span style=\"color: #000000;\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-1308 size-full aligncenter\" src=\"https:\/\/www.anjun.com.tw\/wp-content\/uploads\/2017\/10\/SFG-app-table.png\" sizes=\"(max-width: 541px) 100vw, 541px\" srcset=\"https:\/\/www.anjun.com.tw\/wp-content\/uploads\/2017\/10\/SFG-app-table.png 541w, https:\/\/www.anjun.com.tw\/wp-content\/uploads\/2017\/10\/SFG-app-table-300x133.png 300w\" alt=\"\" width=\"541\" height=\"240\" \/><\/span><\/p><\/div><\/div><\/div><div id=\"panel-1293-1-0-3\" class=\"so-panel widget widget_sow-editor\" data-index=\"5\"><div class=\"so-widget-sow-editor so-widget-sow-editor-base\"><div class=\"siteorigin-widget-tinymce textwidget\"><h3><span style=\"color: #000000;\">3. Applications<\/span><\/h3><h4><span style=\"color: #000000;\">Real time monitoring of:<\/span><\/h4><ul><li><p><span style=\"color: #000000;\">Surface chemical reactions<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">2-D phase transitions<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Surface heating and pressurization<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Effects of potential changes on the electrode in electrolyte<\/span><\/p><\/li><li><p><span style=\"color: #000000;\">Measurements of surface concentration (after calibration)<\/span><\/p><\/li><\/ul><p><span style=\"color: #000000;\">Pump-probe measurements of laser-induced flash heating, shock compression and chemical reactions at surfaces with picosecond time resolution (with optional high-power laser source).<\/span><\/p><\/div><\/div><\/div><div id=\"panel-1293-1-0-4\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"6\"><div class=\"so-widget-sow-editor so-widget-sow-editor-base\"><div class=\"siteorigin-widget-tinymce textwidget\"><h3><span style=\"color: #000000;\">4. PDF &amp; Extras<\/span><\/h3><p><span style=\"text-decoration: underline;\"><a href=\"https:\/\/1drv.ms\/b\/s!AnpRtfok8x0pjTBeHTwXpbgGfVKh\" target=\"_blank\" rel=\"noopener\">SFG &#8211; Vibrational Spectroscopy with a Twist.PDF<\/a><\/span><\/p><p><span style=\"text-decoration: underline;\"><a href=\"https:\/\/1drv.ms\/b\/s!AnpRtfok8x0pjTGxZej3ODQ3wieC\" target=\"_blank\" rel=\"noopener\">Sample positioner for optical surface probe experiments.PDF<\/a><\/span><\/p><\/div><\/div><\/div>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>","protected":false},"excerpt":{"rendered":"<p>Astrolabe tabletop femtosecond SFG\/CARS spectrometer Fe&hellip;&nbsp;<a href=\"https:\/\/www.anjun.com.tw\/en\/%e9%9b%b7%e5%b0%84\/%e9%9b%b7%e5%b0%84%e9%80%b1%e9%82%8a%e8%a8%ad%e5%82%99%e9%8a%b7%e5%94%ae\/atseva%e9%9b%b7%e5%b0%84\/%e5%85%89%e8%ad%9c%e5%84%80\/\" class=\"\" rel=\"bookmark\">Read More &raquo;<span class=\"screen-reader-text\">\u5149\u8b5c\u5100<\/span><\/a><\/p>","protected":false},"author":2,"featured_media":0,"parent":146,"menu_order":16,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"off","neve_meta_content_width":70,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","footnotes":""},"class_list":["post-442","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.0 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>\u5149\u8b5c\u5100 &#060; \u5b89\u5747\u79d1\u6280\u6709\u9650\u516c\u53f8<\/title>\n<meta name=\"description\" content=\"Astrolabe tabletop femtosecond SFG\/CARS spectrometer. 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